Temperature and molecular weight dependence of fracture behaviour of polypropylene films |
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Authors: | B. Fayolle A. Tcharkhtchi J. Verdu |
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Affiliation: | ENSAM 151 Bd de l’Hôpital 75013, Paris, France |
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Abstract: | The effect of temperature on fracture behaviour of isotactic polypropylene films has been studied on two PP samples of molecular weights MW=270 kg mol−1 and MW=150 kg mol−1, using the Essential Work of Fracture method. Two ductile-brittle transitions as a function of temperature are in evidence at respectively 10 and 60 °C. The former transition occurs for the highest molecular weight and the latter one for the lowest molecular weight. Three processes are involved in the temperature effect on PP toughness: (1) The decrease of yield stress with temperature according to Eyring’s law; (2) The role of cooperative motions in the amorphous phase: the ductile-brittle transition of the sample of highest MW corresponds to the glass transition; and (3) The role of the mobility of the crystalline phase: the ductile-brittle transition of the sample of lowest MW corresponds to the C transition. |
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Keywords: | Polypropylene Molecular weight Temperature Ductile fracture EWF |
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