In Situ Monitoring of the Generation of Monodisperse Silica Particles during the Hydrolysis of Tetraethyl Orthosilicate with Piezoelectric Quartz Crystal Impedance Analyzer

The piezoelectric quartz crystal(PQC)impedance analyzer was used to monitor in situ the generation of monodisperse silica particles during the hydrolysis of tetraethyl orthosilicate (TEOS) and their adsorption onto and Au electrode in alcohol solutions containing water(6-15mol/L)and ammonia(0.2-2.0 mol/L).The equivalent circuit parameters,the resonance frequencies and the half-peak width values of the conductance spectra of the PQC resonance were obtained.The resonant frequency decreased notably while the motional resistance changed very slightly(within 1Ω during the hydrolysis reaction,suggesting that the mass effect dominated the adsorption of generated monodisperse silica particles on the gold electrode in this system.Changes in f0 indicated that the ammonia concentration affected the hydrolytic reaction obviously,and the influence of water concentration on the reaction was small while the water was significantly excessive.Kinetics of monodisperse silica particle adsorption occurring at the electrode i solution interface was analyzed using a first-order reaction scheme.In addition,the electrolyte-induced precipitation of the monodisperse silica of adsorbed particles per area and the converge of monodisperse silica particles were obtained from scanning electron nicroscope(SEM)observations.

In Situ Monitoring of the Generation of Monodisperse Silica Particles during the Hydrolysis of Tetraethyl Orthosilicate with Piezoelectric Quartz Crystal Impedance Analyzer

The piezoelectric quartz crystal (PQC) impedance analyzer was used to monitor in situ the generation of monodisperse silica particles during the hydrolysis of tetraethyl orthosilicate (TEOS) and their adsorption onto an Au electrode in alcohol solutions containing water (6–15 mol/L) and ammonia (0.2–2.0 mol/L). The equivalent circuit parameters, the resonance frequencies and the half‐peak width values of the conductance spectra of the PQC resonance were obtained. The resonant frequency decreased notably while the motional resistance changed very slightly (within 1 ω) during the hydrolysis reaction, suggesting that the mass effect dominated the adsorption of generated monodisperse silica particles on the gold electrode in this system. Changes in f₀ indicated that the ammonia concentration affected the hydrolytic reaction obviously, and the influence of water concentration on the reaction was small while the water was significantly excessive. Kinetics of monodisperse silica particle adsorption occurring at the electrode solution interface was analyzed using a first‐order reaction scheme. In addition, the electrolyte‐induced precipitation of the monodisperse silica particles was monitored and discussed. The mean size, the number of adsorbed particles per area and the converge of monodisperse silica particles were obtained from scanning electron microscope (SEM) observations.