Stable,three-coordinate Ni(CO)(2)(NHC) (NHC = N-heterocyclic carbene) complexes enabling the determination of Ni-NHC bond energies |
| |
Authors: | Dorta Reto Stevens Edwin D Hoff Carl D Nolan Steven P |
| |
Institution: | Department of Chemistry, University of New Orleans, New Orleans, LA 70148, USA. |
| |
Abstract: | The synthesis and characterization of three- and four-coordinate Ni(CO)n(NHC) (n = 2, 3; NHC = N-heterocyclic carbene) complexes are reported. Reactions with CO of the Ni(CO)2(NHC) complexes lead to the quantitative formation of Ni(CO)4. Investigation of this reaction under equilibrium conditions allows for the determination of Ni-NHC bond dissociation energies. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|