| 均相催化反应在任一给定形状微电极上的稳态电化学行为 |
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| 引用本文： | 苏连永,罗瑾.均相催化反应在任一给定形状微电极上的稳态电化学行为[J].高等学校化学学报,1994,15(11):1682-1685. |
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| 作者姓名： | 苏连永 罗瑾 |
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| 作者单位： | 厦门大学化学系, 厦门, 361005 |
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| 摘 要： | 根据反应层的概念对在任一给定形状微电极上进行的准一级和二级均相催化反应机理(EC'')的稳态电化学行为进行了研究。本方法简便易行,不需要解复杂方程的数学技巧。利用推导出的这些方程,可计算准一级和二级均相催化反应的动力学常数。
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| 关 键 词： | 微电极 反应层 均相催化反应 稳态电化学行为 |
| 收稿时间： | 1993-01-21 |
The Steady State Electrochemical Behavior of Homogeneous Catalytic Reactions at Microelectrodes of Any Given Geometry |
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| SU Lian-Yong,LUO Jin,LIN Zhong-Hua,TIAN Zhao-Wu.The Steady State Electrochemical Behavior of Homogeneous Catalytic Reactions at Microelectrodes of Any Given Geometry[J].Chemical Research In Chinese Universities,1994,15(11):1682-1685. |
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| Authors: | SU Lian-Yong LUO Jin LIN Zhong-Hua TIAN Zhao-Wu |
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| Institution: | Department of Chemistry, Xiamen University, Xiamen, 361005 |
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| Abstract: | The steady state electrochemical behavior of the pseudo-first and second order homogeneous catalytic reactions at a microelectrode of any given geometry is discussed in this paper.The mathematical treatment of the microelectrode using the concept of reaction layer is simple and is possible to avoid using complicated mathematical skills, By using these equations, some methods for determining kinetic parameters for the pseudo first order and second order CE''reactions are presented. |
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| Keywords: | Microelectrode Reaction layer Homogeneous catalytic reaction Steady stateelectrochemical behavior |
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