Construction of a functional layered solid using the tetrakis(imidazolyl)borate coordinating anion |
| |
Authors: | Hamilton Barton H Kelly Kathryn A Wagler Todd A Espe Matthew P Ziegler Christopher J |
| |
Affiliation: | Department of Chemistry, Knight Chemical Laboratory, University of Akron, Akron, OH 44325, USA. |
| |
Abstract: | The coordination polymer Pb[B(Im)(4)](NO(3)), constructed by using tetrakis(imidazolyl)borate and lead(II) nitrate solutions, is a layered material with the metal centers facing the interlayer spacing. As in naturally occurring layered minerals, this compound can readily undergo anion exchange in the solid state with retention of crystallinity. We examined stoichiometric exchange of (15)N-nitrate for nitrate and iodide for nitrate by (15)N and (207)Pb SSNMR and confirmed retention of crystallinity by IR and powder XRD diffraction. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|