Crystal Structure and Catalytic Properties of Tetrakis（4-hydroxyphenyl）Porphyrinato Manganese （Ⅲ） Chloride （MnTHPPCI）

The crystal structure of meso-tetrakis （4-hydroxyphenyl） porphyrinato manganese chloride （MnTHPPC1） and its supramolecular architecture based on the hydrogen bonds of one counter C1 anion with four hydrogen atoms of four-OH groups from different MnTHPPC1 molecules cooperated by self-assembly of the porphyrin units were first repor-ted. This compound crystallized in the tetragonal space group 14/m with a = 1.39928（7） nm, b = 1.39928（7） nm, c =0.94498（10） nm, V= 1.8503（2） nm^3, and Z =2. As a catalyst, MnTHPPC1 also showed a high catalytic acti-vity in the conversion from 1-naphthylamine （1-NA） to his （4-oxo-benzo-2-cyclohexen-l-yl） amine （BOBCHA） v/a oxidative coupling under mild conditions.

Crystal Structure and Catalytic Properties of Tetrakis (4-hydroxyphenyl) Porphyrinato Manganese (III) Chloride (MnTHPPCI)

The crystal structure of meso-tetrakis (4-hydroxyphenyl) porphyrinato manganese chloride (MnTHPPCl) and its supramolecular architecture based on the hydrogen bonds of one counter Cl anion with four hydrogen atoms of four -OH groups from different MnTHPPCl molecules cooperated by self-assembly of the porphyrin units were first reported. This compound crystallized in the tetragonal space group I4/m with a = 1.39928(7) nm, b = 1.39928(7) nm,c =0.94498(10) nm, V = 1.8503(2) nm3, and Z = 2.As a catalyst, MnTHPPCl also showed a high catalytic activity in the conversion from 1-naphthylamine (1-NA) to bis (4-oxo-benzo-2-cyclohexen-1-yl) amine ( BOBCHA ) via oxidative coupling under mild conditions.