Hydrogen-broadening coefficients in the ν7 band of ethylene at low temperature |
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Authors: | Jean-Pierre Bouanich Ghislain Blanquet Muriel Lepère |
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Institution: | a Laboratoire de Photophysique Moléculaire, UPR3361 du CNRS, Université de Paris-Sud, Bâtiment 350, F-91405 Orsay cedex, France b Laboratoire de Spectroscopie Moléculaire, Facultés Universitaires Notre-Dame de la Paix, 61, rue de Bruxelles, B-5000 Namur, Belgium |
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Abstract: | H2-broadening coefficients have been measured for 35 lines of C2H4 at 173.2 K in the P, Q, and R branches of the ν7 fundamental band near 10 μm, using a tunable diode-laser spectrometer. These lines were individually fitted with a Voigt and a Rautian profile to determine their collisional widths. The resulting broadening coefficients, as well as those previously measured at room temperature are compared with values calculated on the basis of a semiclassical model of interacting linear molecules, using an atom-atom Lennard-Jones potential in addition to the weak electrostatic contributions. A satisfactory agreement is obtained for the results at room temperature, but the theoretical results at low temperature are generally smaller than the experimental data. Finally, the temperature dependence of the broadening coefficients has been determined both experimentally and theoretically. |
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Keywords: | Tunable diode-laser Ethylene Hydrogen Broadening coefficients Semiclassical theory |
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