| 碱光诱导激基缔合物的振动结构的荧光发射 |
| |
| 引用本文： | 雷学工,谢锐强,刘有成. 碱光诱导激基缔合物的振动结构的荧光发射[J]. 化学学报, 1989, 47(10): 1032-1034 |
| |
| 作者姓名： | 雷学工 谢锐强 刘有成 |
| |
| 作者单位： | 兰州大学化学系 |
| |
| 基金项目： | 国家自然科学基金，教委资助优秀年青教师基金资助课题 |
| |
| 摘 要： | 本文研究在1:1的甲醇-水二元溶剂, RNA及各碱基诱导的1,3-2(2-萘基)丙烷(1)的激光缔合物的振动结构的荧光发射, 振动结构的出现是由于RNA及各碱基诱导1分子按一定几何构象“冻结"使其振动能级固定的结果, 而高φ值下的疏水的相互作用只是促进了这一过程, 当加入β-CD时, 产生的振动结构会消失, 而加入α-CD则不受影响。
|
| 关 键 词： | 荧光分析 核糖核酸 溶剂 环糊精 诱导物 振动分析 激基缔合物 包合物 结构 微环境效应 |
RNA and bases induced vibrational structures of excimer fluorescence |
| |
| LEI XUEGONG,XIE RUIQIANG,LIU YOUCHENG. RNA and bases induced vibrational structures of excimer fluorescence[J]. Acta Chimica Sinica, 1989, 47(10): 1032-1034 |
| |
| Authors: | LEI XUEGONG XIE RUIQIANG LIU YOUCHENG |
| |
| Abstract: | Significant vibrational structures of fluorescence emission of excimers of 1,3-di(a-naphthyl)propane (1) in 1:1 methanol-water binary solvent was induced by the addition of RNA or its constitutive bases. It is suggested that RNA and base mols. induce the 1 mols. to freeze with proper conformation and give a definite excited vibration, and this process was promoted by hydrophobic effect. Inductive vibrational structure formation can be prevented by the addition of b-cyclodextrin, but is not disturbed by the addition of a-cyclodextrin, indicating partial inclusion of 1 mols. by b-cyclodextrin. |
| |
| Keywords: | FLUORIMETRIC ANALYSIS RIBONUCLEIC ACID SOLVENTS CYCLODEXTRIN INDUCER FLUTTER ANALYSIS EXCIMER CLATHRATES STRUCTURE MICROENVIRONMENTAL EFFECTS |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《化学学报》浏览原始摘要信息 |
|
点击此处可从《化学学报》下载全文 |
|
