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Oxidation of 1-alkylcycloalkanols with PbIV and MnIII compounds under mechanical activation |
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| Authors: | N I Kapustina L L Sokova V D Makhaev L A Petrova G I Nikishin |
| Institution: | 1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation 2. Institute of New Chemical Problems, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation |
| Abstract: | A mechanoactivated solid-state oxidative decyclization of 1-alkylcycloalkanols under the action of the Pb(OAc)4?MX or Mn(OAc)3?MX systems (MX is a metal halide) was carried out for the first time. The reaction affords exclusively ω-haloalkanones. |
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