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Miniemulsion cross-linking: A convenient route to hollow polymeric nanocapsule with a liquid core
Authors:Lin Wu  Tao Pang  Ye-bin Guan
Institution:1. Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering,Anqing Normal University, Anqing 246011, China;Anhui Collaborative Innovation Center for Petrochemical New Materials, Anqing 246011, China;2. Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering,Anqing Normal University, Anqing 246011, China
Abstract:Miniemulsion stabilized by poly(2-(dimethylamino) ethyl methacrylate)-block-poly(butyl methylacrylate) (PDMAEMA-b-PBMA) diblock copolymers has been used as liquid templates for the synthesis of polymer nanocapsules via quaternization cross-linking of PDMAEMA segments of the copolymer by 1,2-bis(2-iodoethoxy)ethane (BIEE) crosslinkers. PDMAEMA-b-PBMAs here as a stabilizer in miniemulsion with different molecular weights led to a size variation in diameters of nanocapsules, demonstrating the capsules have potential design capability of this technique. The solution behavior of the capsules has been also investigated in this paper.
Keywords:Cross-linking  Miniemulsion  Nanocapsule  Block copolymer
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