Miniemulsion cross-linking: A convenient route to hollow polymeric nanocapsule with a liquid core |
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Authors: | Lin Wu Tao Pang Ye-bin Guan |
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Institution: | 1. Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering,Anqing Normal University, Anqing 246011, China;Anhui Collaborative Innovation Center for Petrochemical New Materials, Anqing 246011, China;2. Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering,Anqing Normal University, Anqing 246011, China |
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Abstract: | Miniemulsion stabilized by poly(2-(dimethylamino) ethyl methacrylate)-block-poly(butyl methylacrylate) (PDMAEMA-b-PBMA) diblock copolymers has been used as liquid templates for the synthesis of polymer nanocapsules via quaternization cross-linking of PDMAEMA segments of the copolymer by 1,2-bis(2-iodoethoxy)ethane (BIEE) crosslinkers. PDMAEMA-b-PBMAs here as a stabilizer in miniemulsion with different molecular weights led to a size variation in diameters of nanocapsules, demonstrating the capsules have potential design capability of this technique. The solution behavior of the capsules has been also investigated in this paper. |
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Keywords: | Cross-linking Miniemulsion Nanocapsule Block copolymer |
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