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Low-valence palladium complexes: Stoichiometric reactions and catalysis
Authors:I I Moiseev  T A Stromnova  M N Vargaftik
Institution:(1) N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907 Moscow, Russian Federation
Abstract:New data on the structure and reactivity of palladium clusters are surveyed. The mechanisms of stoichiometric and catalytic reactions of the palladium cluster complexes with alkenes, alcohols, aldehydes, formic acid, CO, and phenol are discussed. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 807–815, March, 1998.
Keywords:palladium  clusters  catalytic activity
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