| Transfer Hydrogenation of Acetophenone Catalyzed by in situ Generated 2,6-Bis(5-thioxo-4,5-dihydro-1,2,4-triazole- 3-yl)pyridine-ruthenium(II) Complexes |
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| 引用本文： | CET&#,N Ahmet,DAYAN Osman. Transfer Hydrogenation of Acetophenone Catalyzed by in situ Generated 2,6-Bis(5-thioxo-4,5-dihydro-1,2,4-triazole- 3-yl)pyridine-ruthenium(II) Complexes[J]. 中国化学, 2009, 27(5): 978-982. DOI: 10.1002/cjoc.200990166 |
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| 作者姓名： | CET&# N Ahmet DAYAN Osman |
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| 作者单位： | a Department of Chemistry, Sciences and Arts Faculty, Bingöl University, 12000, Bingol, Turkey ;b Department of Chemistry, Sciences and Arts Faculty, Çanakkale Onsekiz Mart University, 17100 ;Canakkale, Turkey ; |
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| 摘 要： | 2,6-Bis(5-thioxo-4,5-dihydro-1,2,4-triazole-3-yl)pyridines (3, 4) were used for the first time as ligand in ruthenium catalyzed transfer hydrogenation of acetophenone. The in situ prepared three-component system Ru(II)/tridentate triamine ligands (3a—3d, 4a—4d) and KOH catalysed the transfer hydrogenation reaction of acetophenone in good yields under mild conditions.
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| 关 键 词： | transfer hydrogenation tridentate triamine ligand 2 6-bis(5-thioxo-4 5-dihydro-1 2 4-triazole-3- yl)pyridine |
| 收稿时间： | 2008-10-30 |
| 修稿时间： | 2009-01-08 |
Transfer Hydrogenation of Acetophenone Catalyzed by in situ Generated 2,6-Bis(5-thioxo-4,5-dihydro-1,2,4-triazole- 3-yl)pyridine-ruthenium(Ⅱ) Complexes |
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| CETIN,Ahmet,DAYAN,Osman. Transfer Hydrogenation of Acetophenone Catalyzed by in situ Generated 2,6-Bis(5-thioxo-4,5-dihydro-1,2,4-triazole- 3-yl)pyridine-ruthenium(Ⅱ) Complexes[J]. Chinese Journal of Chemistry, 2009, 27(5): 978-982. DOI: 10.1002/cjoc.200990166 |
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| Authors: | CETIN Ahmet DAYAN Osman |
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| Affiliation: | Department of Chemistry, Sciences and Arts Faculty, Bing?l University, 12000, Bingol, Turkey |
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| Abstract: | 2,6‐Bis(5‐thioxo‐4,5‐dihydro‐1,2,4‐triazole‐3‐yl)pyridines ( 3 , 4 ) were used for the first time as ligand in ruthenium catalyzed transfer hydrogenation of acetophenone. The in situ prepared three‐component system Ru(II)/tridentate triamine ligands ( 3a – 3d , 4a – 4d ) and KOH catalysed the transfer hydrogenation reaction of acetophenone in good yields under mild conditions. |
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| Keywords: | transfer hydrogenation tridentate triamine ligand 2,6‐bis(5‐thioxo‐4,5‐dihydro‐1,2,4‐triazole‐3‐ yl)pyridine |
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