Binuclear ladder-type complexes as building blocks for the synthesis of novel polynuclear systems |
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| Authors: | T. Yu. Orlova Yu. S. Nekrasov |
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| Affiliation: | 1.A. N. Nesmeyanov Institute of Organoelement Compounds,Russian Academy of Sciences,Moscow,Russian Federation |
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| Abstract: | Summarized are reactivity studies of binuclear ladder complexes in the metallation reaction that has been applied to prepare novel homo- and heteropolynuclear transition metal complexes. The electron transfer through π-ligand-metal-σ,π-ligand-metal chain has been studied by IR spectroscopy and cyclic voltammetry techniques. |
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