Copper-containing catalysts for the oxidative dehydrogenation of organic compounds |
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| Authors: | O N Krasnobaeva I P Belomestnykh T A Nosova T A Elizarova G V Isagulyants V P Danilov |
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| Institution: | 1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia
2. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, Moscow, 119991, Russia
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| Abstract: | A method of doping magnesium aluminum hydrotalcites, which are precursors for oxidative dehydrogenation oxide catalysts of various compositions, with copper(II) was developed, and copper(II)-containing oxide catalyst samples were synthesized. The catalytic properties of these catalysts were studied in the oxidative dehydrogenation of ethane, propane, and hexane. The conversion of ethane into ethylene on the copper-containing catalysts was established to proceed with high selectivities (90?C97%) and at low temperatures (400?C450°C). |
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