PREPARATION OF α-KETOPHOSPHONATES BY OXIDATION OF α-HYDROXYPHOSPHONATES WITH PYRIDINIUM CHLOROCHROMATE (PCC) |
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Authors: | Habib Firouzabadi Nasser Iranpoor Sara Sobhani |
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Institution: | Department of Chemistry, College of Sciences, Shiraz University , Shiraz, Iran |
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Abstract: | Various types of diethyl α-hydroxyphosphonates were converted efficiently to their corresponding diethyl α-ketophosphonates by pyridiinum chlorochromate (PCC) without cleavage of C(O)─P bond in the absence of solvent or in solution in high yields. |
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Keywords: | α-Hydroxyphosphonates α-ketophosphonates chlorochromates oxidation |
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