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PREPARATION OF α-KETOPHOSPHONATES BY OXIDATION OF α-HYDROXYPHOSPHONATES WITH PYRIDINIUM CHLOROCHROMATE (PCC)
Authors:Habib Firouzabadi  Nasser Iranpoor  Sara Sobhani
Institution:Department of Chemistry, College of Sciences, Shiraz University , Shiraz, Iran
Abstract:Various types of diethyl α-hydroxyphosphonates were converted efficiently to their corresponding diethyl α-ketophosphonates by pyridiinum chlorochromate (PCC) without cleavage of C(O)─P bond in the absence of solvent or in solution in high yields.
Keywords:α-Hydroxyphosphonates  α-ketophosphonates  chlorochromates  oxidation
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