Microwave Induced Reaction of H-Dimethylphosphonate with Styrene Oxide |
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Authors: | S. Munavalli D. K. Rohrbaugh G. W. Wagner F. R. Longo H. D. Durst |
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Affiliation: | 1. Gunpowder Branch, APG , Geo-Centers, Inc. , Maryland;2. Edgewood Chemical Biological Center, APG , U. S. Army , Maryland |
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Abstract: | Microwave catalyzed reaction of a neat mixture of styrene oxide and H-dimethylphosphonate furnished dimethyl methylphosphonate, trimethylphosphate, phenylacetaldehyde, 1-methoxy-2-phenylethanol, 1-phenylethleneglycol, cis- and trans-1,3-diphenylcyclobutanes, hydrogen 1-(2-phenylethyl)methylphosphinate, (1-phenylethyl)dimethylphosphonate, and (1-phenylethyl)dimethylphosphonate via free radical processes. |
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Keywords: | Free Radical Reaction H-phosphonate Hydrophosphorylation Styrene Oxide |
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