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Microwave Induced Reaction of H-Dimethylphosphonate with Styrene Oxide
Authors:S Munavalli  D K Rohrbaugh  G W Wagner  F R Longo  H D Durst
Institution:1. Gunpowder Branch, APG , Geo-Centers, Inc. , Maryland;2. Edgewood Chemical Biological Center, APG , U. S. Army , Maryland
Abstract:Microwave catalyzed reaction of a neat mixture of styrene oxide and H-dimethylphosphonate furnished dimethyl methylphosphonate, trimethylphosphate, phenylacetaldehyde, 1-methoxy-2-phenylethanol, 1-phenylethleneglycol, cis- and trans-1,3-diphenylcyclobutanes, hydrogen 1-(2-phenylethyl)methylphosphinate, (1-phenylethyl)dimethylphosphonate, and (1-phenylethyl)dimethylphosphonate via free radical processes.
Keywords:Free Radical Reaction  H-phosphonate  Hydrophosphorylation  Styrene Oxide
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