ALANINE/CHLOROCHROMIC ACID/SILICA GEL: AN EFFICIENT AND SELECTIVE REAGENT FOR THE OXIDATION OF ORGANIC FUNCTIONAL GROUPS |
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| Authors: | Peyman Salehi Mohammad Mehdi Khodaei Amin Rostami |
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| Institution: | 1. Department of Phytochemistry, Medicinal Plants Research Institute, Shahid Beheshti University , Tehran, Iran;2. , 19835-389;3. Department of Chemistry, Faculty of Science, Razi University , Kermanshah, Iran |
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| Abstract: | Alanine/chlorochromic acid/silica gel is a new and selective reagent for the efficient oxidation of sulfides, thiols, oximes, and alcohols. Oxidation of sulfides is solvent dependent. In chloroform at room temperature sulfoxides are formed as the major products, while in carbon tetrachloride or under solvent-free conditions solfones are produced in good-to-excellent yields. |
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| Keywords: | Alcohols chlorochromic acid oxidation oximes sulfides thiols |
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