The Reactions of Hexachlorocyclotriphosphazatriene with Ligands Including Mercapto Groups |
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Authors: | Saliha Begeç Sümeyya Alataş |
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Institution: | Chemistry Department , Inonu University , Malatya , Turkey |
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Abstract: | In this work, the reactions of hexachlorocyclotriphosphazatriene (trimer), N 3 P 3 Cl 6 1, with 2-mercapto-1-methylimidazole (methimazole) 2, 2-mercaptopyrimidine 3, and 2-mercaptopyridine 4 were discussed. Mono- (5) and pentasubstituted (6) phosphazenes were obtained from the reaction of 1 with 2-mercapto-1-methylimidazole. Both mono- (7) and disubstituted geminal (8) phosphazenes were obtained from the reaction of 1 with 2-mercaptopyrimidine. But phoshazene or any phosphorus compound could not be isolated from the reaction of 1 with 2-mercaptopyridine. |
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Keywords: | Hexachlorocyclotriphosphazatriene imidazole methimazole pyridine pyrimidine |
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