Synthesis and Multinuclear NMR Study of Benzoyl Methylene Triparatolylphosphorane Ylide and the Reaction of this Ylide with Mercury(II) Halides |
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| Authors: | Seyyed Javad Sabounchei A R Dadrass Sepideh Samiee |
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| Institution: | Chemistry Department , Bu-Ali-Sina University , Hamadan , Iran |
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| Abstract: | The reaction of the title ylide {PhCOCHP(p-tolyl)3} with Pd(II), Pt(II). Hg(II), and Ag(I) in equimolar ratios using CH3CN, CH3OH, and CH2Cl2 as solvents have yielded {(p-tolyl)3PCHCOC6H5} PdCl2]2 (I), {(p-tolyl)3 PCHCOC6H5} PtCl2]2(2), Hg(NO3)2 {(p-tolyl)3 PCHCOC6H5}](3), and Ag{(p-tolyl)3 PCHCOC6H5 < eqid1 > 2]+ (4). The IR, 1H 13C, and 31P NMR together with micro analysis data of the products were obtained. |
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| Keywords: | Benzoylmethylentriparatolylphosphorane mercury(II) palladium(II) platinum(II) silver(I) |
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