Einige Neue N,S-Substituierte 2-Nitrodienverbindungen Aus Reaktionen Von Mono(p-fluorarylthio)substituierten Dienen Mit Aminen |
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Authors: | Cemil İbiş Murat Onul |
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Affiliation: | Fakult?t für Ingeniurwesen Istanbul Universit?t , Avcilar-Istanbul, Türkei |
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Abstract: | 2-Nitrodiene compound 1 was stirred with p-fluorothiophenol for a long time and compound 3 was obtained. Compound 1 gave bis(thio)substituted 2-nitrodiene compound 4 and tris(thio)substituted compound 5 with 2 moles of p-fluorothiophenol in the presence of NaOH in ethanol. The compounds 9a–g have been prepared from 8a–g and 3. Compound 7 was obtained from the reaction of mono(thio)substituted 2-nitrodiene with morpholine. Compound 3 gives 11a–d in the reaction with piperidines in CH2Cl2 (or ether). Compound 13a–b have been obtained from the reaction of compound 3 with primary amines 12a–b. Compound 3 gives 15 and 16 in the reaction with 2,5-dimethylpiperazine in CH2Cl2. |
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Keywords: | 1,3-Halonitrodiene p-Fluorothiophenol piperazine piperidine S-, S,S-, N,S-substituted 1,3-halonitrodienes thioether thiols |
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