A Convenient One-Pot Synthesis of Di-t-butylphosphinic Chloride |
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| Authors: | Daniel F. Brayton Karen I. Goldberg Werner Kaminsky D. Michael Heinekey |
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| Affiliation: | Department of Chemistry , University of Washington , Seattle, Washington, USA |
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| Abstract: | A convenient one-pot synthesis of (t-Bu)2P(O)Cl (1) from m-chloroperbenzoic acid and (t-Bu)2PCl is described. The byproduct m-chlorobenzoic acid is neutralized by addition of Et3N. Complex 1 crystallizes in the monoclinic space group P21/c (No. 14), with a = 5.9637(2) Å, b = 11.4734(4) Å, c = 16.2400(5) Å and β = 107.7160(14). |
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| Keywords: | Chemical synthesis crystal structure phosphinic chloride |
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