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Photo-Trifluoromethylthiolation of Cyclopropyl Phenyl Propargyl Alcohol |
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| Authors: | S Munavalli D I Rossman D K Rohrbaugh H D Durst |
| Institution: | 1. Geo-Centers, Inc. , Aberdeen Proving Ground, Maryland, 21010;2. Edgewood Chemical Biological Center , U.S. Army , Aberdeen Proving Ground, Maryland, 21010 |
| Abstract: | Seven compounds are formed in various amounts when a solution of cyclopropopyl phenyl propargyl alcohol and trifluoromethylsulfenyl chloride in acetonitrile is exposed to UV light. The probable mechanism of formation and the mass spectral characterization of these compounds are described. |
| Keywords: | Cyclopropyl Ring Cleavage Trifluoromethylthiyl And Chlorine Radical Addition And Substitution |