Synthesis,Crystal Structure,and Luminescence of a Three-Dimensional Supramolecular Compound Based on a Dinuclear Tin Cluster |
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| Authors: | Wenxiang Chai Li Song Hangyan Shen Kangying Shu |
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| Affiliation: | 1. College of Materials Science and Engineering , China Jiliang University , Hangzhou, People's Republic of China;2. Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Education Ministry, Department of Chemistry , Zhejiang Sci-Tech University , Hangzhou, People's Republic of China |
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| Abstract: | A three-dimensional (3D) supramolecular compound, [(phen)LSnS]2·(H2O)2 (phen = 1,10-phenanthroline, L = mercaptoacetic acid), has been synthesized and the crystal structure was determined by a single crystal X-ray diffraction study. 1 is triclinic, space group P-1 with a = 6.695(1) Å, b = 10.929(2) Å, c = 12.117(2) Å, α = 114.55(3)°, β = 93.53(2)°, γ = 104.06(3)°, and Z = 1. The dinuclear cluster of [(phen)LSnS]2 and H2O are linked into a 3D supramolecular framework by a combination of O[sbnd]H…O, C[sbnd]H…O hydrogen bonds and π–π stacking interactions. Its luminescence property is discussed. |
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| Keywords: | Crystal structure dinuclear tin cluster hydrogen bonding supramolecular π–π stacking |
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