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INORGANIC RINGS WITH GALLIUM ORGANYLS AND IMINODIPHOSPHINECHALCHOGENIDES |
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| Authors: | Sara Cortés-Llamas Cristian Silvestru Miguel-Ángel Muñoz-Hernández |
| Institution: | Universidad Autónoma del Estado de Morelos , Morelos, México |
| Abstract: | The organometallic complexes of general formula Me 2 Ga{(XPR 2 ) (YPR′ 2 )N}] (R, R′ = Ph, X, Y = O, (1); R, R′ = Ph, X, Y = S (2); R, R′ = Ph, X = O, Y = S (3); R = Me, R′ = Ph, X = O, Y = S (4)) were obtained by alkane eliminations from Me 3 Ga and the free acidic ligands, LH, in toluene solutions. Complexes 1– 4 seem to be potential precursors to cationic gallium species. |
| Keywords: | Cations iminodiphosphinechalchogenides organogallium complexes |