Synthesis and Characterization of Aminophosphines,Bis(amino)phosphine Derivatives,and Their Molybdenum(0) Complexes |
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| Authors: | Özlem Sarıöz Osman Serindaĝ Meysun İ. Abdullah |
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| Affiliation: | 1. Department of Chemistry, Faculty of Science-Arts , Ni ?de University , Ni?de, Turkey;2. Department of Chemistry, Faculty of Science-Arts , ?ukurova University , Adana, Turkey |
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| Abstract: | Functionalized bis(amino)phosphines of the type PhP(NHR)2 ( 1a–c ) and aminophosphines of the type Ph2PNHR ( 2a–c ) have been synthesized by treating PhPCl2 or Ph2PCl with corresponding primary amines of H2N-R where R = -CH2SO3H, -C6H4SO3H, and benzo-15-crown-5. The molybdenum(0) complex of the aminophosphine ( 3 ) has been obtained by reacting cis-[Mo(CO)4(bipy)] with aminophosphine ( 2c ). The synthesized aminophosphines, bis(amino)phosphines, and the molybdenum(0) complex have been characterized by IR, 1H NMR, 31P NMR, and MS spectroscopic techniques and by elemental analysis. |
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| Keywords: | Aminophosphine bis(amino)phosphines crown ethers molybdenum(0) complexes |
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