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An Efficient and Selective Oxidation of Sulfides and Thiols with Silica-Supported 1,1,3,3-Tetramethylguanidine/Br2 Complex
Authors:Ahmad Shaabani  Elham Farhangi  Abbas Rahmati
Affiliation:Department of Chemistry , Shahid Beheshti University , Tehran, Iran
Abstract:Silica-supported 1,1,3,3-tetramethylguanidine/Br2 complex is an efficient reagent for the selective oxidation of aliphatic and aromatic sulfides to the corresponding sulfoxides and the oxidative coupling of thiols to disulfides in aqueous solution at room temperature in a short reaction time.
Keywords:Oxidation  silica-supported 1,1,3,3-tetramethylguanidine/Br2 complex  sulfide  thiol
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