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On the Reaction of 3-Acetyl Coumarin with Alkyl Phosphites. Structural Confirmations Based on X-Ray Crystallography
Authors:Fayez H Osman  Naglaa M Abd El-Rahman  Fatma A El-Samahy  I S Ahmed Farag
Institution:National Research Center , Dokki, Cairo, Egypt
Abstract:3-Acetyl coumarin ( 1 ) reacts with dialkyl phosphites at 100°;C for 8 h to give the phosphonates 2 . Under the same experimental conditions, 1 reacts with trialkyl phosphites to form a mixture of the phosphonates 2 and 3 . The molecular structures of these products were elucidated by x-ray crystallography.
Keywords:3-Acetyl Coumarin  Alkyl Phosphites  x-ray Crystallography
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