OXIDATIVE DEPROTECTION OF TRIMETHYLSILYL ETHERS TO CARBONYL COMPOUNDS WITH PdCI2(PhCN)2-CrO3 AND CLAY-BIS(TRIMETHYLSILYL) CHROMATE IN SOLVENTLESS SYSTEM |
| |
| Authors: | Majid M Heravi Dariush Ajami Kioumars Aghapoor Mitra Ghassemzadeh |
| |
| Institution: | 1. Chemistry &2. Chemical Engineering Research Center of Iran , P.O. Box 14335-186, Tehran , Iran |
| |
| Abstract: | Abstract A simple and selective oxidative deprotection of trimethylsilyl ethers to carbony1 compounds is described that occurs on PdCl2(PhCN)2-CrO3 and bis(trimethylsily1) chromate under solvent free conditions and is expedited by microwave irradiation. |
| |
| Keywords: | carboxyesters pseudopeptides thrombin thrombin inhibitors |
|
