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Preparation of N-Arylsulfonyl Imines from Sulfonamides and Aryl Aldehydes Using Magnesium Oxide as a Heterogeneous and Reusable Catalyst Under Solvent-Free Conditions
Authors:Alireza Hasaninejad  Abdolkarim Zare  Ahmad Reza Moosavi Zare  Abolfath Parhami  Hashem Sharghi  Ali Khalafi-Nezhad
Institution:1. Department of Chemistry, Faculty of Sciences , Persian Gulf University , Bushehr , Iran;2. Department of Chemistry , Payame Nour University (PNU) , Iran;3. Department of Chemistry , College of Sciences, Shiraz University , Shiraz , Iran
Abstract:An efficient solvent-free procedure for the preparation of N-arylsulfonyl imines from sulfonamides and aryl aldehydes in the presence of a catalytic amount of magnesium oxide and tetrabutylammonium bromide (TBAB) under microwave irradiation is described. The advantages of this method are good to high yields, short reaction times, low cost, and matching with green chemistry protocols.
Keywords:Aldehyde  magnesium oxide  microwave  N-arylsulfonyl imine  solvent-free  sulfonamide
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