Microwave-Assisted Reaction of Dimethyl H-Phosphonate with Cyclohexene and Alkene Oxides |
| |
| Authors: | H D Durst D K Rohrbaugh S Munavalli |
| |
| Institution: | 1. U.S. Army Edgewood Chemical Biological Center , Aberdeen Proving Ground, Maryland, USA;2. SAIC , Gunpowder Branch, Aberdeen Proving Ground, Maryland, USA |
| |
| Abstract: | Microwave-assisted reaction of dimethyl H-phosphonate with cyclohexene-, 1,2-butene-, and 1,2-decene oxides furnishes 8, 5, and 17 compounds, respectively. The probable mechanism of the formation of the various compounds via free radical reactions and their GC-MS characterization are presented in this article. |
| |
| Keywords: | Butyl and decyl derivatives cyclohexyl deoxygenation diastereomeric phosphonates and pyrophosphates dimethyl H-phosphonate free radical reaction mass spectral breakdown behavior |
|
|
