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PYRIDINIUM SULFONATE CHLOROCHROMATE (VI), C5H5NSO3H [CrO3Cl] (PSCC): A NEW REAGENT FOR OXIDATION OF ORGANIC SUBSTRATES
Authors:M. Z. Kassaee  A. R. Bekhradnia
Affiliation:Department of Chemistry, Faculty of Science, Tarbiat Modarres University , Tehran, Iran
Abstract:A fast, mild, and reasonable oxidizing agent, pyridinium sulfonate chlorochromate (VI), C5H5NSO3H [CrO3Cl] (PSCC) is synthesized. Its reactions with primary, secondary, benzylic, and allylic alcohols under very mild conditions give the corresponding carbonyl compounds. These are obtained with relatively short reaction times. The oxidant/substrate ratios of 1:1 are employed.
Keywords:Carbonyl compounds  oxidation of alcohols
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