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Synthesis and Spectroscopic Properties of Mixed Aryloxide-Glycolate Derivatives of Arsenic(III)
Authors:Sunita Goyal  Anirudh Singh
Institution:University of Rajasthan , Jaipur, India
Abstract:The reaction in 1:1 molar ratio of {\gg4}OGOAsCl , where G = CH 2 CH 2 , CHMeCHMe, CMe 2 CMe 2 , CHMeCH 2 CMe 2 , and CMe 2 CH 2 CH 2 CMe 2 , and substituted phenols ArOH (Ar = C 6 H 3 Me 2 -2,6; C 6 H 3 Pr i -5-Me-2; C 6 H 3 Pr i -2-Me-5 and C 6 H 3 Pr i 2 -2,6), in the presence of one equivalent of triethylamine in benzene afford volatile colorless liquids of the type {\gg4}OGOAsOAr . All these derivatives have been characterized by elemental analyses, molecular weight measurements, and spectroscopic IR, NMR( 1 H and 13 C)] studies.
Keywords:Arsenic(III) Derivatives  Aryloxides  Aryloxide-glycolate Derivatives
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