Synthesis and Characterization of Some New Organoantimony(III) Derivatives of N,S Donor Bifunctional Tetradentate Schiff Bases |
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Authors: | Rajendra K. Sharma Audhesh K. Rai Yashpal Singh |
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Affiliation: | University of Rajasthan , Jaipur, India |
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Abstract: | Reactions of triphenylantimony(III) with the corresponding Schiff bases in equimolar ratios yield the phenylantimony(III) derivatives, PhSb[RC(NC 6 H 4 S)CH 2 (NC 6 H 4 S)CCOOCH 3 ] (R = C 6 H 5 , 4-ClC 6 H 4 , 4-BrC 6 H 4 , and 4-CH 3 C 6 H 4 ). These derivatives have been characterized by elemental analyses, molecular weight measurements, and IR as well as NMR ( 1 H and 13 C) spectral studies which reveal a five coordination around the central antimony atom. |
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Keywords: | Five Coordinated Antimony(III) Schiff Bases Triphenylantimony(III) |
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