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Coordination Chemistry of a Bulky 1,3-Diphosphapropene with Carbonyltungsten(0) Moieties
Authors:Shigekazu Ito  Masaaki Yoshifuji
Institution:Department of Chemistry, Graduate School of Science , Tohoku University , Sendai , Japan
Abstract:( Z )-2-Chloro-3,3-diphenyl-1-(2,4,6-tri- t -butylphenyl)-1,3-diphosphapropene was derived from chlorodiphenylphosphine and 1-chloro-2-(2,4,6-tri- t -butylphenyl)-2-phosphaethenyllithium and utilized for complex formations as a ligand of the corresponding carbonyl-tungsten(0) complexes.
Keywords:Coordination  1  3-diphosphapropene  Kinetic Stabilization  Phosphorus  Tungsten
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