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Electron Spin Resonance study of gamma irradiated MA-AMPS copolymer
Authors:V Sridhar  Veera Bhadraiah  G Punnaiah  Sanjeeva Rao  Subbarami Reddy
Institution:1. Department of Chemistry , Kakatiya University , Warangal, 506 009, India;2. Department of Polymer Science , Sri Krishnadevaraya University , Ananthapur, 515 003, India
Abstract:

Electron Spin Resonance (ESR) spectra of gamma irradiated methylacrylamide-2-acrylamido-2-methyl-propanesulphonic acid (MA-AMPS) are recorded to identify the radical species formed during the irradiation of the copolymer. The ESR spectrum observed for irradiated MA-AMPS copolymer at liquid nitrogen temperature (LNT) (77 r K) is an asymmetric triplet; while the spectrum observed at room temperature (RT) is a quintet. The intensity distribution of both the spectra deviated appreciably from the expected theoretical values. Computer simulations are employed to analyze the ESR spectra observed at different temperatures. The triplet spectrum observed at LNT is simulated to be a superposition of component spectra arising from macroradicals of the type~CH 2 - \dot {\rm C} H-CH 2 ~ (I), radicals of the type \dot {\rm C} H 2 SO 3 H (II), and peroxy radicals (III). In contrast, the RT spectrum is simulated to be a superposition of component spectra arising due to radicals I, II, III together with the component quartet assigned to methyl radicals ( \dot {\rm C} H 3 ). The formation of such free radicals in irradiated copolymer is discussed.
Keywords:Esr  Ftir  Ma-AMPS  Irradiation  Computer Simulation
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