HEXAMETHYLDISILAZANE IN THE PRESENCE OF N,N′,N″,N?-TETRAMETHYLTETRA-2,3-PYRIDINOPORPHYRAZINATO COPPER (II) IS A NEW,MILD AND HIGHLY EFFICIENT REAGENT FOR SILYLATION OF ALCOHOLS AND PHENOLS |
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Authors: | Batool Akhlaghinia Mozafar Asadi Elham Safaee Mozhgan Heydarpoor |
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Institution: | 1. Department of Chemistry, Damghan University of Basic Sciences , Damghan, Iran;2. Department of Chemistry, Faculty of Sciences, Shiraz University , Shiraz, Iran |
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Abstract: | Alcohols and phenols are protected with hexamethyldisilazane in the presence of N,N′,N′,N?-tetramethyletra-2,3-pyridinoporphyrazinato copper (II) in good-to-excellent yields at room temperature. |
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Keywords: | Alcohols hexamethyldisilazane (HMDS) N N′ N″ N? -tetramethyltetra-2 3-pyridinoporphyrazinato copper (II) phenols silylation |
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