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Carbonylation of Lithium Enolates of Esters and Amides with Carbon Monoxide and Selenium |
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| Authors: | Nobuaki Kambe Akira Nishiyama Shin-Ichi Fujiwara Tsutomu Shin-Ike Noboru Sonoda |
| Institution: | 1. Department of Molecular Chemistry, Graduate School of Engineering, Osaka University , Suita , Osaka , Japan;2. Department of Chemistry, Osaka Dental University , Hirakata , Osaka , Japan;3. Department of Applied Chemistry, Faculty of Engineering, Kansai University , Suita , Osaka , Japan |
| Abstract: | Abstract Lithium enolates of esters, amides, and an acylsilane undergo carbonylation with carbon monoxide with the aid of selenium under mild conditions to yield the corresponding selenol esters after trapping with alkyl iodides. |
| Keywords: | Amide carbon monoxide carbonylation ester lithium enolate selenium |