Pd-catalyzed regio- and stereoselective cyclization-heck reaction of monoesters of 1,2-allenyl phosphonic acids with alkenes |
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| Authors: | Yu Fei Lian Xiongdong Ma Shengming |
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| Affiliation: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, People's Republic of China. |
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| Abstract: | [reaction: see text] The cyclization-Heck reactions of monoesters of 1, 2-allenyl phosphonic acids with alkenes were studied. The reaction afforded 4-(1-Z-alkenyl)-2-ethoxy-2,5-dihydro[1,2]oxaphosphole 2-oxides regio- and stereoselectively. Pd(II) was regenerated from the in situ formed Pd(0) using CaH2(cat.)/NaI/O2 or benzoquinone to furnish the catalytic cycle. |
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