On the peroxidation reactions of monomolybdates |
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Authors: | Liszhi J Csányi |
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Institution: | (1) Lastitute of Inorganic and Analytical Chemistry, A. József University, P.O. Box 440, 6701 Szeged, Hungary |
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Abstract: | Summary The differences in kinetic behaviour of the reactions between MoVI and H2O2 in media at different pH are explained by the involvement of different MoVI species. In acidic medium a 6-coordinate MoVI undergoes an H+-independent substitution, while in neutral or alkaline solutions a proton-assisted addition takes place between the 4-coordinate MoVI and H2O2. |
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