Spectroscopic characterisation of indium(III) chloride and mixed ligand complexes |
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Authors: | Kloo Lars Taylor Michael J |
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Affiliation: | Inorganic Chemistry, Royal Institute of Technology, Stockholm, Sweden. |
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Abstract: | Acidic solutions of InCl3 plus InBr3 contain mixed halide complexes and solvent extraction yields the four-coordinate anions InCl(n)Br(4 - n)-, whose v(In-Cl) and v(In-Br) modes are reported. Two solid products of InCl3 with 15-crown-5 have been identified; crystallisation from aqueous HCI gave a molecular adduct containing InCl3(H2O)2, whereas the ionic complex [InCl2(15-crown-5)][InCl4] was produced under anhydrous conditions. The vibrational spectra are assigned. |
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