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| THE FIRST BINUCLEAR MOLYBDENUM AND TUNGSTEN COMPLEXES WITH DOUBLY-BRIDGING PYRIDINE-2-THIOLATO LIGANDS.X-RAY CRYSTAL STRUCTURE OF THE COMPLEX[Mo_2(CO)_4(μ-pyS)_2(PPh_3)_2].2C_7H_8 | |
| 摘 要： | The title complex was obtained by reactions ofMo(CO)_3(MeCN)_3] with CuBr(pySH)(PPh_3)_2]or directly with pySH and PPh_3.The latter method can be used to synthesize the corresponding tungstencomplex W_2(CO)_4(μ-pyS)_2(PPh_3)_2].The molecular structure of the titlecompound was determined by X-ray diffraction method. |
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