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A new oxime ligand in manganese chemistry: a [Mn8] and a [Mn6] cage from the use of 2-dihydroxy-2-phenylacetamidine |
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| Authors: | Flamourakis Andreas G Tzimopoulos Demetrios Siczek Milosz Lis Tadeusz O'Brien James R Akrivos Pericles D Milios Constantinos J |
| Affiliation: | Department of Chemistry, University of Crete, 71003, Herakleion, Greece. |
| Abstract: | The use of phamidoxH(2) (phamidoxH(2) = 2-dihydroxy-2-phenylacetamidine) in manganese cluster chemistry led to the synthesis and characterization of a hexametallic and an octametallic Mn(III) cluster, both of which display a S = 3 ground state. |
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