Enhanced glutathione peroxidase activity of conformationally restricted naphthalene peri-dichalcogenides |
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Authors: | Press David J Back Thomas G |
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Institution: | Department of Chemistry, University of Calgary, Calgary, Alberta, Canada, T2N 1N4. |
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Abstract: | Conformationally restricted naphthalene peri-diselenides function as glutathione peroxidase mimetics with superior catalytic activity to that displayed by typical acyclic diaryl diselenides. Their activity was increased by electron-donating methoxy substituents, while a further 100-fold increase was observed with the corresponding ditelluride. |
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