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Light-induced reactions of 1,1,1-trifluoro-3-decyn-2-one with olefins |
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| Authors: | P. Margaretha C. Schr der S. Wolff W. C. Agosta |
| Affiliation: | Institut für Organische Chemie, Universität Hamburg, M.L. King Platz 6 D-2000 Hamburg 13 F.R.G. Laboratories of the Rockefeller University, New York, NY 10021 U.S.A. |
| Abstract: | Irradiation ( λ = 300 nm) of 1,1,1-trifluoro-3-decyn-2-one in the presence of olefins affords RH-reduction products (tertiary alcohols) in addition to [2+2] -(oxetans) and [3+2] -(dihydrofurans) cycloadducts. |
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