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Solubility of nonpolar gases in 2,2,2-trifluoroethanol at 25°C and 101.33 kPa partial pressure of gas
Authors:Ana M Mainar  Juan Pardo  Félix M Royo  María C López  José S Urieta
Institution:1. Departamento de Química Orgánica-Química Física, Facultad de Ciencias, Universidad de Zaragoza, Ciudad Universitaria, 50009, Zaragoza, Spain
Abstract:Solubility measurements of several nonpolar gases (He, Ne, Ar, Kr, Xe, H2, N2, CH4, C2H4, C2H6, CF4, SF6, and CO2) in 2,2,2-trifluoroethanol at 25°C and 101.33 kPa partial pressure of gas are reported. Gibbs energy for the solution process at 25°C is evaluated from the experimental values of the solubility of gases expressed as mole fraction. Lennard-Jones 6–12 pair potential parameters for 2,2,2-trifluoroethanol are estimated by using the scaled particle theory (SPT); and experimental solubilities are compared with those calculated from the values of these parameters through the SPT model.
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