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Versatile new uranyl(VI) dihalide complexes supported by tunable organic amide ligands
Authors:Kannan Shanmugaperumal  Barnes Charles L  Duval Paul B
Affiliation:Department of Chemistry, University of Missouri-Columbia, 601 S. College Ave., Columbia, MO 65211, USA.
Abstract:
A series of uranyl(VI) dihalide complexes UO2X2L2 (X = Cl, Br) supported by organic amide ligands (L = R'C(O)NR2; R' = i-Pr; R = i-Pr, i-Bu, s-Bu) offers the versatile combination of facile synthesis using benchtop methods, air-stable crystalline solids obtained in high yield, high solubility in common organic solvents and tunable steric/electronic properties.
Keywords:
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