The depth of molecular recognition: voltage-sensitive blockage of synthetic multifunctional pores with refined architecture |
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Authors: | Baudry Yoann Pasini Dario Nishihara Masamichi Sakai Naomi Matile Stefan |
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Affiliation: | Department of Organic Chemistry, University of Geneva, Switzerland. |
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Abstract: | Voltage-sensitive blockage by ADP, ATP and phytate (IP6) demonstrates that active-site contraction toward the middle of newly synthesized rigid-rod beta-barrels provides a general strategy to rationally create and modulate the voltage sensitivity (and to increase the efficiency) of molecular recognition by synthetic multifunctional pores. |
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