Gas phase thermolysis of cyclohexyl thiol |
| |
Authors: | N Barroeta G Martin and J Capasso |
| |
Institution: | (1) Centro de Química Instituto Venezolano de Investigaciones Científicas, Apartado 1827, Caracas, Venezuela;(2) Present address: INTEVEP, Apartado 76343, 107 Caracas, Venezuela |
| |
Abstract: | The pyrolysis of cyclohexyl thiol has been studied in a static system at subambient pressures in the temperature range 420–497°C. It is proposed that in the presence of a large excess of cyclohexene the mechanism is a radical non-chain process.
![Pcy](/content/r6701n67212x1351/xxlarge1055.gif) ![icy](/content/r6701n67212x1351/xxlarge1080.gif) ![rcy](/content/r6701n67212x1351/xxlarge1088.gif) ![ocy](/content/r6701n67212x1351/xxlarge1086.gif) ![lcy](/content/r6701n67212x1351/xxlarge1083.gif) ![icy](/content/r6701n67212x1351/xxlarge1080.gif) ![tscy](/content/r6701n67212x1351/xxlarge1094.gif) ![icy](/content/r6701n67212x1351/xxlarge1080.gif) ![kcy](/content/r6701n67212x1351/xxlarge1082.gif) ![lcy](/content/r6701n67212x1351/xxlarge1083.gif) ![ocy](/content/r6701n67212x1351/xxlarge1086.gif) ![gcy](/content/r6701n67212x1351/xxlarge1075.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![kcy](/content/r6701n67212x1351/xxlarge1082.gif) ![scy](/content/r6701n67212x1351/xxlarge1089.gif) ![icy](/content/r6701n67212x1351/xxlarge1080.gif) ![lcy](/content/r6701n67212x1351/xxlarge1083.gif) ![tcy](/content/r6701n67212x1351/xxlarge1090.gif) ![icy](/content/r6701n67212x1351/xxlarge1080.gif) ![ocy](/content/r6701n67212x1351/xxlarge1086.gif) ![lcy](/content/r6701n67212x1351/xxlarge1083.gif) ![bcy](/content/r6701n67212x1351/xxlarge1073.gif) ![ycy](/content/r6701n67212x1351/xxlarge1099.gif) ![icy](/content/r6701n67212x1351/xxlarge1080.gif) ![scy](/content/r6701n67212x1351/xxlarge1089.gif) ![scy](/content/r6701n67212x1351/xxlarge1089.gif) ![lcy](/content/r6701n67212x1351/xxlarge1083.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![dcy](/content/r6701n67212x1351/xxlarge1076.gif) ![ocy](/content/r6701n67212x1351/xxlarge1086.gif) ![vcy](/content/r6701n67212x1351/xxlarge1074.gif) ![acy](/content/r6701n67212x1351/xxlarge1072.gif) ![pcy](/content/r6701n67212x1351/xxlarge1087.gif) ![rcy](/content/r6701n67212x1351/xxlarge1088.gif) ![dcy](/content/r6701n67212x1351/xxlarge1076.gif) ![acy](/content/r6701n67212x1351/xxlarge1072.gif) ![vcy](/content/r6701n67212x1351/xxlarge1074.gif) ![lcy](/content/r6701n67212x1351/xxlarge1083.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![ncy](/content/r6701n67212x1351/xxlarge1085.gif) ![icy](/content/r6701n67212x1351/xxlarge1080.gif) ![yacy](/content/r6701n67212x1351/xxlarge1103.gif) , ![ncy](/content/r6701n67212x1351/xxlarge1085.gif) ![icy](/content/r6701n67212x1351/xxlarge1080.gif) ![zhcy](/content/r6701n67212x1351/xxlarge1078.gif) ![acy](/content/r6701n67212x1351/xxlarge1072.gif) ![tcy](/content/r6701n67212x1351/xxlarge1090.gif) ![mcy](/content/r6701n67212x1351/xxlarge1084.gif) ![ocy](/content/r6701n67212x1351/xxlarge1086.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![fcy](/content/r6701n67212x1351/xxlarge1092.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![rcy](/content/r6701n67212x1351/xxlarge1088.gif) ![ncy](/content/r6701n67212x1351/xxlarge1085.gif) ![ycy](/content/r6701n67212x1351/xxlarge1099.gif) , ![icy](/content/r6701n67212x1351/xxlarge1080.gif) ![ncy](/content/r6701n67212x1351/xxlarge1085.gif) ![tcy](/content/r6701n67212x1351/xxlarge1090.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![rcy](/content/r6701n67212x1351/xxlarge1088.gif) ![vcy](/content/r6701n67212x1351/xxlarge1074.gif) ![acy](/content/r6701n67212x1351/xxlarge1072.gif) ![lcy](/content/r6701n67212x1351/xxlarge1083.gif) ![tcy](/content/r6701n67212x1351/xxlarge1090.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![mcy](/content/r6701n67212x1351/xxlarge1084.gif) ![pcy](/content/r6701n67212x1351/xxlarge1087.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![rcy](/content/r6701n67212x1351/xxlarge1088.gif) ![acy](/content/r6701n67212x1351/xxlarge1072.gif) ![tcy](/content/r6701n67212x1351/xxlarge1090.gif) ![ucy](/content/r6701n67212x1351/xxlarge1091.gif) 420–497°C. ![Pcy](/content/r6701n67212x1351/xxlarge1055.gif) ![ocy](/content/r6701n67212x1351/xxlarge1086.gif) ![lcy](/content/r6701n67212x1351/xxlarge1083.gif) ![acy](/content/r6701n67212x1351/xxlarge1072.gif) ![gcy](/content/r6701n67212x1351/xxlarge1075.gif) ![acy](/content/r6701n67212x1351/xxlarge1072.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![tcy](/content/r6701n67212x1351/xxlarge1090.gif) ![scy](/content/r6701n67212x1351/xxlarge1089.gif) , ![chcy](/content/r6701n67212x1351/xxlarge1095.gif) ![tcy](/content/r6701n67212x1351/xxlarge1090.gif) ![pcy](/content/r6701n67212x1351/xxlarge1087.gif) ![rcy](/content/r6701n67212x1351/xxlarge1088.gif) ![icy](/content/r6701n67212x1351/xxlarge1080.gif) ![scy](/content/r6701n67212x1351/xxlarge1089.gif) ![ucy](/content/r6701n67212x1351/xxlarge1091.gif) ![tcy](/content/r6701n67212x1351/xxlarge1090.gif) ![scy](/content/r6701n67212x1351/xxlarge1089.gif) ![tcy](/content/r6701n67212x1351/xxlarge1090.gif) ![vcy](/content/r6701n67212x1351/xxlarge1074.gif) ![icy](/content/r6701n67212x1351/xxlarge1080.gif) ![bcy](/content/r6701n67212x1351/xxlarge1073.gif) ![ocy](/content/r6701n67212x1351/xxlarge1086.gif) ![lcy](/content/r6701n67212x1351/xxlarge1083.gif) ![softcy](/content/r6701n67212x1351/xxlarge1100.gif) ![shchcy](/content/r6701n67212x1351/xxlarge1097.gif) ![icy](/content/r6701n67212x1351/xxlarge1080.gif) ![icy](/content/r6701n67212x1351/xxlarge1080.gif) ![zcy](/content/r6701n67212x1351/xxlarge1079.gif) ![bcy](/content/r6701n67212x1351/xxlarge1073.gif) ![ycy](/content/r6701n67212x1351/xxlarge1099.gif) ![tcy](/content/r6701n67212x1351/xxlarge1090.gif) ![kcy](/content/r6701n67212x1351/xxlarge1082.gif) ![ocy](/content/r6701n67212x1351/xxlarge1086.gif) ![tscy](/content/r6701n67212x1351/xxlarge1094.gif) ![icy](/content/r6701n67212x1351/xxlarge1080.gif) ![kcy](/content/r6701n67212x1351/xxlarge1082.gif) ![lcy](/content/r6701n67212x1351/xxlarge1083.gif) ![ocy](/content/r6701n67212x1351/xxlarge1086.gif) ![gcy](/content/r6701n67212x1351/xxlarge1075.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![kcy](/content/r6701n67212x1351/xxlarge1082.gif) ![scy](/content/r6701n67212x1351/xxlarge1089.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![ncy](/content/r6701n67212x1351/xxlarge1085.gif) ![pcy](/content/r6701n67212x1351/xxlarge1087.gif) ![rcy](/content/r6701n67212x1351/xxlarge1088.gif) ![ocy](/content/r6701n67212x1351/xxlarge1086.gif) ![tscy](/content/r6701n67212x1351/xxlarge1094.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![scy](/content/r6701n67212x1351/xxlarge1089.gif) ![pcy](/content/r6701n67212x1351/xxlarge1087.gif) ![rcy](/content/r6701n67212x1351/xxlarge1088.gif) ![ocy](/content/r6701n67212x1351/xxlarge1086.gif) ![tcy](/content/r6701n67212x1351/xxlarge1090.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![kcy](/content/r6701n67212x1351/xxlarge1082.gif) ![acy](/content/r6701n67212x1351/xxlarge1072.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![pcy](/content/r6701n67212x1351/xxlarge1087.gif) ![ncy](/content/r6701n67212x1351/xxlarge1085.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![rcy](/content/r6701n67212x1351/xxlarge1088.gif) ![acy](/content/r6701n67212x1351/xxlarge1072.gif) ![dcy](/content/r6701n67212x1351/xxlarge1076.gif) ![icy](/content/r6701n67212x1351/xxlarge1080.gif) ![kcy](/content/r6701n67212x1351/xxlarge1082.gif) ![acy](/content/r6701n67212x1351/xxlarge1072.gif) ![lcy](/content/r6701n67212x1351/xxlarge1083.gif) ![softcy](/content/r6701n67212x1351/xxlarge1100.gif) ![ncy](/content/r6701n67212x1351/xxlarge1085.gif) ![ocy](/content/r6701n67212x1351/xxlarge1086.gif) ![gcy](/content/r6701n67212x1351/xxlarge1075.gif) ![pcy](/content/r6701n67212x1351/xxlarge1087.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![pcy](/content/r6701n67212x1351/xxlarge1087.gif) ![ncy](/content/r6701n67212x1351/xxlarge1085.gif) ![ocy](/content/r6701n67212x1351/xxlarge1086.gif) ![mcy](/content/r6701n67212x1351/xxlarge1084.gif) ![mcy](/content/r6701n67212x1351/xxlarge1084.gif) ![iecy](/content/r6701n67212x1351/xxlarge1077.gif) ![khcy](/content/r6701n67212x1351/xxlarge1093.gif) ![acy](/content/r6701n67212x1351/xxlarge1072.gif) ![ncy](/content/r6701n67212x1351/xxlarge1085.gif) ![icy](/content/r6701n67212x1351/xxlarge1080.gif) ![zcy](/content/r6701n67212x1351/xxlarge1079.gif) ![mcy](/content/r6701n67212x1351/xxlarge1084.gif) .
|
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|