Formation of radicals during dimethyldioxirane decomposition |
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| Authors: | N N Kabal'nova D V Kazakov N M Shishlov V V Shereshovets |
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| Institution: | (1) Institute of Organic Chemistry, Ural Branch of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation |
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| Abstract: | Thermal decomposition of dimethyldioxirane is followed by the formation of radicals registered by ESR spectroscopy using aC-phenyl-N-tert-butylnitronc spin trap. The intensity of the ESR signal increases linearly with increasing temperature; the dependence is extreme in character.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1552–1554, June, 1996. |
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| Keywords: | organic peroxides dimethyldioxirane spin trap |
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